The topic is an emerging hot area of NMR and crystallography. It includes methods of measurement and computation of dipolar coupling constants and chemical shifts, the aim being to obtain detailed information about crystal structures. The total methodology is complementary to that of diffraction methods, especially as regards matters of molecular-level mobility and structural disorder. Generally, single crystals are not required so microcrystalline powders are used. The techniques can be used alongside diffraction measurements for the full structural characterization of such powdered materials. Applications to a wide range of chemistry will be discussed. All aspects of NMR theory, methodology and applications, which provide information on crystal structure and molecular-level dynamics therein. The aim will be to explore both how crystal structure affects NMR and how NMR gives data on crystal structure. This monograph will be a must for everybody working in solid-state physics and chemistry, in crystallography and in materials science